This is the theme song to the 1985 James Bond movie of the same name starring Roger Moore and Grace Jones. It is the only theme from a Bond movie to hit #1 in America.
The story behind this song, according to the bassist John Taylor, was that he approached the longtime Bond producer, Albert R. 'Cubby' Broccoli, while extremely intoxicated when they were both at a party. He stated that he was a long time fan (Major Bond geek would be more accurate. An Aston Martin was said to be one of his first "rock star" purchases, and he frequently mentioned his Bond video collection in interviews) of the series, but the music for the last few movies had been mediocre. He then offered to have his band fix the problem and Broccoli took the idea under advisement.
If you are a complete Duran Duran nut, you will notice during the video that there seems to be communication between three band members (Le Bon, Rhodes, and Roger Taylor), while the other two members (John and Andy Taylor) are doing things like shooting the deployed cameras and setting Rhodes's ear mike to explode. John and Andy were the members who left for Power Station. The other three made up the band Arcadia.
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