The extra "R" in "Herre" is there to indicate that it is really hot. Definitely hotter than just one "R." It's also a written expression of the St. Louis accent, where Nelly is from. Christina Aguilera did the same thing on her song, "Dirrty," which needed the extra "R" because it was really dirty. Another rap hit from the time, "Right Thurr" by Chingy (also from St. Louis), used the extra R as well.
This was produced by The Neptunes, who are the team of Chad Hugo and Pharrell Williams. In addition to their own group N.E.R.D, they produced for Jay Z, Snoop Dogg, Justin Timberlake, Britney Spears, and many others, specializing in high-energy hip-hop beats. Nelly makes reference the producers in the line, "Nelly took a trip from the Luna to Neptunes."
The groove is based on "Bustin' Loose," a huge go-go hit for Chuck Brown & The Soul Searchers released in 1978. Nelly's line "I feel like bustin' loose" also comes from that track.
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